For thermal waves, calculate the magnitude of the group velocity. This shows that the thermal diffusion equation cannot hold exactly since the velocity of propagation can become larger than that of any particles that could carry heat through the material. We now consider a modification of the thermal diffusion equation which fixes this problem. Consider the number density n of thermal carriers in a material. In equilibrium, n=n0, so that
(∂t∂n)=−v⋅∇n+τn−n0,(10.79)
where τ is a relaxation time and v is the carrier velocity. Multiply this equation by ωτv, where ω is the energy of a carrier, and sum over all k states. Using the fact that ∑kn0v=0 and J=∑kωnv, and that ∣n−n0∣≪n0 show that
J+τdtdJ=−κ∇T,(10.80)
and hence the modified thermal diffusion equation becomes
∂t∂T+τ∂t2∂2T=D∇2T.(10.81)
Show that this modified equation gives a group velocity whose magnitude remains finite. Is this modification ever necessary?