A laboratory procedure calls for 1.50L of an acetate buffer whose total acetate species concentration ([CH₃COOH] + [CH₃COO⁻]) is 0.30M and whose pH is 4.46 (pKa of acetic acid = 4.76). How many grams of sodium acetate trihydrate (NaCH₃COO·3H₂O, molar mass = 136g mol−1) must be weighed out?
a) 14.1g
b) 20.4g
c) 40.8g
d) 30.6g