Chemistry

Chemistry

Problem

Two unlabeled potential-energy curves, X and Y, are described as follows. • Curve X has its minimum at 0.74 Å with a value of –946 kJ·mol⁻¹. • Curve Y has its minimum at 1.09 Å with a value of –436 kJ·mol⁻¹. Which statement correctly assigns the curves to the O=O double bond and the O–O single bond in molecular oxygen species? a) Curve X represents the O–O single bond, and Curve Y represents the O=O double bond. b) Both curves could represent either bond because bond order affects energy but not equilibrium distance. c) Curve X represents the O=O double bond, and Curve Y represents the O–O single bond. d) Curve X represents the O–O single bond because single bonds are stronger (deeper well) than double bonds; Curve Y represents the O=O double bond.

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