Introduction to Quantum Mechanics · Problem 8.18

The Variational Principle — David J. Griffiths

Physics — Quantum Mechanics · variational_harmonic_oscillator

Problem

(a) Generalize Problem 8.2, using the trial wave function ψ(x)=A(x2+b2)n,\psi(x) = \frac{A}{(x^2 + b^2)^n}, for arbitrary nn. *Partial answer:* The best value of bb is given by b2=ℏmω[n(4n−1)(4n−3)2(2n+1)]1/2.b^2 = \frac{\hbar}{m\omega}\left[\frac{n(4n-1)(4n-3)}{2(2n+1)}\right]^{1/2}. (b) Find the least upper bound on the first excited state of the harmonic oscillator using a trial function of the form ψ(x)=Bx(x2+b2)n.\psi(x) = \frac{Bx}{(x^2 + b^2)^n}. *Partial answer:* The best value of bb is given by b2=ℏmω[n(4n−5)(4n−3)2(2n+1)]1/2.b^2 = \frac{\hbar}{m\omega}\left[\frac{n(4n-5)(4n-3)}{2(2n+1)}\right]^{1/2}. (c) Notice that the bounds approach the exact energies as n→∞n \to \infty. Why is that? *Hint:* Plot the trial wave functions for n=2n = 2, n=3n = 3, and n=4n = 4, and compare them with the true wave functions (Equations 2.60 and 2.63). To do it analytically, start with the identity ez=lim⁡n→∞(1+zn)n.e^z = \lim_{n\to\infty}\left(1 + \frac{z}{n}\right)^n.

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