Chemistry

Chemistry

Problem

Which of the following best explains why the two C–O bond lengths in the formate ion, $ \mathrm{HCO}_{2}^-$, are identical and intermediate between a typical C=O double bond and a C–O single bond? a) Each C–O\text{C–O} bond alternates between single and double character because the bonds rapidly switch positions in time. b) Because the carbon atom is sp2\text{sp}^2-hybridized, both C–O\text{C–O} bonds must have identical lengths regardless of bond order. c) Electron delocalization produces a resonance hybrid in which each C–O\text{C–O} bond has a fractional bond order between 1 and 2. d) Steric repulsion between the two oxygen atoms forces the C–O\text{C–O} bonds to adopt identical lengths.

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