Chemistry

Chemistry

Problem

When the aqueous reaction between Sn2+(aq)\mathrm{Sn^{2+}(aq)} and MnO4−(aq)\mathrm{MnO_4^{-}(aq)} is carried out at pH 1, balancing the chemical equation requires inserting H2O\mathrm{H_2O} molecules rather than OH−\mathrm{OH^-} ions. Which of the following statements best explains this requirement? a) OH−\mathrm{OH^-} would neutralize the acidic medium (pH 1), altering the reaction conditions, so H2O\mathrm{H_2O} is used instead. b) The high concentration of H+\mathrm{H^+} in the medium enables H2O\mathrm{H_2O} to supply oxygen atoms while maintaining charge neutrality. c) In acidic solutions the balancing procedure actually calls for OH−\mathrm{OH^-} to remove excess H+\mathrm{H^+}, but because the pH is already so low only H2O\mathrm{H_2O} is added. d) OH−\mathrm{OH^-} would precipitate manganese as Mn(OH)2\mathrm{Mn(OH)_2}, so it cannot appear in the balanced equation.

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