Chemistry

Chemistry

Problem

The rusting of iron takes place as follows : 2H++2e−+1/2O2⟶H2O(l)2\text{H}^+ + 2e^- + 1/2\text{O}_2 \longrightarrow \text{H}_2\text{O} (\text{l}) ; E∘=+1.23 VE^{\circ} = +1.23 \text{ V} Fe2++2e−⟶Fe(s)\text{Fe}^{2+} + 2e^- \longrightarrow \text{Fe} (\text{s}) ; E∘=−0.44 VE^{\circ} = -0.44 \text{ V} The ΔG∘\Delta G^{\circ} for the net process is : (IIT 2005) a. −322 kJ mol−1-322 \text{ kJ mol}^{-1} b. −161 kJ mol−1-161 \text{ kJ mol}^{-1} c. −152 kJ mol−1-152 \text{ kJ mol}^{-1} d. −76 kJ mol−1-76 \text{ kJ mol}^{-1}

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