Callen H.B - Thermodynamics And An Introduction To Thermostatistics · Problem 15.4-2

THE CANONICAL FORMALISM; STATISTICAL MECHANICS IN HELMHOLTZ REPRESENTATION

Physics — Statistical Mechanics · polymer-model-elimination

Problem

Eliminate U/εU/\varepsilon between equations 15.23 and 15.24 and show that the formal solution is equation 15.25 with a ±\pm sign before the second term in the denominator. Consider the qualitative dependence of Lx/N~aL_x/\tilde{N}a on ε\varepsilon, and show that physical reasoning rejects the negative sign in the denominator, thus validating equation 15.25.

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