Introduction to Quantum Mechanics · Problem 5.37

Identical Particles — David J. Griffiths

Physics — Quantum Mechanics · density_of_states

Problem

An important quantity in many calculations is the density of states G(E)G(E): G(E) dE≡number of states with energy between E and E+dE.G(E)\, dE \equiv \text{number of states with energy between } E \text{ and } E + dE. For a one-dimensional band structure, G(E) dE=2(dq2π/Na),G(E)\, dE = 2 \left( \frac{dq}{2\pi/Na} \right), where dq/(2π/Na)dq/(2\pi/Na) counts the number of states in the range dqdq (see Equation 5.63), and the factor of 2 accounts for the fact that states with qq and −q-q have the same energy. Therefore 1NaG(E)=1π1∣dE/dq∣.\frac{1}{Na} G(E) = \frac{1}{\pi} \frac{1}{|dE/dq|}. (a) Show that for α=0\alpha = 0 (a free particle) the density of states is given by 1NaGfree(E)=1πℏm2E.\frac{1}{Na} G_{\text{free}}(E) = \frac{1}{\pi \hbar} \sqrt{\frac{m}{2E}}. (b) Find the density of states for α≠0\alpha \neq 0 by differentiating Equation 5.71 with respect to qq to determine dE/dqdE/dq. Note: Your answer should be written as a function of EE only (well, and α\alpha, mm, ℏ\hbar, aa, and NN) and must not contain qq (use kk as a shorthand for 2mE/ℏ\sqrt{2mE}/\hbar, if you like). (c) Make a single plot showing G(E)/NaG(E)/Na for both α=0\alpha = 0 and α=1\alpha = 1 (in units where m=ℏ=a=1m = \hbar = a = 1). Comment: The divergences at the band edges are examples of van Hove singularities.

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