Introduction to Quantum Mechanics · Problem 7.9

Time-Independent Perturbation Theory — David J. Griffiths

Physics — Quantum Mechanics · degenerate_perturbation_theory

Problem

Consider a particle of mass mm that is free to move in a one-dimensional region of length LL that closes on itself (for instance, a bead that slides frictionlessly on a circular wire of circumference LL, as in Problem 2.46). (a) Show that the stationary states can be written in the form ψn(x)=1Le2πinx/L,(−L/2<x<L/2),\psi_n(x) = \frac{1}{\sqrt{L}}e^{2\pi inx/L}, \quad (-L/2 < x < L/2), where n=0,±1,±2,…n = 0, \pm 1, \pm 2, \ldots, and the allowed energies are En=2m(nπℏL)2.E_n = \frac{2}{m}\left(\frac{n\pi\hbar}{L}\right)^2. Notice that—with the exception of the ground state (n=0n = 0)—these are all doubly degenerate. (b) Now suppose we introduce the perturbation H′=−V0e−x2/a2,H' = -V_0 e^{-x^2/a^2}, where a≪La \ll L. (This puts a little "dimple" in the potential at x=0x = 0, as though we bent the wire slightly to make a "trap".) Find the first-order correction to EnE_n, using Equation 7.33. *Hint:* To evaluate the integrals, exploit the fact that a≪La \ll L to extend the limits from ±L/2\pm L/2 to ±∞\pm\infty; after all, H′H' is essentially zero outside −a<x<a-a < x < a. (c) What are the "good" linear combinations of ψn\psi_n and ψ−n\psi_{-n}, for this problem? (*Hint:* use Eq. 7.27.) Show that with these states you get the first-order correction using Equation 7.9. (d) Find a hermitian operator AA that fits the requirements of the theorem, and show that the simultaneous eigenstates of H0H^0 and AA are precisely the ones you used in (c).

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