Statistical Mechanics · Problem 5.8

The Theory of Simple Gases — R. K. Pathria

Physics — Statistical Mechanics · peierls-inequality

Problem

Prove the following theorem due to Peierls: ``If H^\hat{H} is the hermitian Hamiltonian operator of a given physical system and {ϕn}\{\phi_n\} an arbitrary orthonormal set of wave functions satisfying the symmetry requirements and the boundary conditions of the problem, then the partition function of the system satisfies the following inequality: Q(β)≥∑nexp⁡{−β⟨ϕn∣H^∣ϕn⟩};Q(\beta) \geq \sum_n \exp\left\{-\beta\langle\phi_n|\hat{H}|\phi_n\rangle\right\}; the equality holds when {ϕn}\{\phi_n\} is a complete orthonormal set of eigenfunctions of the Hamiltonian itself.''

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