Chemistry

Chemistry

Problem

A gaseous reaction has ΔH∘=−198 kJ\Delta H^\circ=-198\,\text{kJ} (exothermic). Which statement best describes how its equilibrium constant KK changes when the temperature is raised from 298 K298\,\text{K} to 350 K350\,\text{K}? a) The effect on KK cannot be predicted without knowing the sign of ΔS∘\Delta S^{\circ}. b) KK increases because higher temperature favors the forward reaction for any gas–phase equilibrium. c) KK decreases because heat acts as a product, so adding heat shifts the equilibrium toward reactants. d) KK remains essentially constant because temperature affects the rate of reaction, not the equilibrium constant.

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