JEE Advanced 2013 Paper 2 Chemistry Q14

Chemistry · Titrations: Acid-Base, Complexometric, Redox, Precipitation

Problem

Paragraph for Questions 13 and 14 An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCl\ce{HCl}, gave a precipitate (PP) and a filtrate (QQ). The precipitate PP was found to dissolve in hot water. The filtrate (QQ) remained unchanged when treated with HX2S\ce{H2S} in a dilute mineral acid medium. However, it gave a precipitate (RR) with HX2S\ce{H2S} in an ammoniacal medium. The precipitate RR gave a coloured solution (SS), when treated with HX2OX2\ce{H2O2} in an aqueous NaOH\ce{NaOH} medium. The coloured solution SS contains

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