Chemistry

Chemistry

Problem

In a calibration experiment a student obtained the relationship A=(1.25×104)cA=(1.25\times10^{4})c for a series of solutions measured in a 1.00 cm cuvette. Which of the following is the best interpretation of the numerical value 1.25×1041.25\times10^{4}? a) It is the concentration (in mol L−1^{-1}) at which the analyte absorbs 1 \% of the incident light. b) It is the molar absorptivity of the analyte, expressed in L mol−1 cm−1\text{L\,mol}^{-1}\,\text{cm}^{-1}, at the chosen wavelength. c) It equals twice the path length multiplied by the molar absorptivity of the analyte. d) It is the slope of the calibration plot and therefore has units L mol−1\text{L\,mol}^{-1}, because the 1.00 cm path length cancels the cm−1\text{cm}^{-1} term.

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