Chemistry

Chemistry

Problem

Acetone, (CH₃)₂C=O, is a polar solvent in which the carbonyl oxygen bears a partial negative charge and the carbonyl carbon bears a partial positive charge. When Ca²⁺ ions dissolve in liquid acetone, which orientation of acetone molecules in the first solvation shell is most likely? a) The carbonyl carbon atoms point toward the Ca2+\mathrm{Ca^{2+}} ion because they are partially positive. b) The carbonyl oxygen atoms point toward the Ca2+\mathrm{Ca^{2+}} ion because they are partially negative. c) The methyl hydrogen atoms point toward the Ca2+\mathrm{Ca^{2+}} ion because they are the least electronegative part of the molecule. d) The acetone molecules remain randomly oriented because ion–dipole forces are negligible in acetone.

Browse the problem library