Chemistry

Chemistry

Problem

Which of the following statements about the relationship among ΔG°, the equilibrium constant K, and kinetic control is MOST accurate? a) When KK is very large, the activation energy must also be low, ensuring a fast reaction. b) A negative ΔG∘\Delta G^{\circ} implies K>1K>1, but the reaction may still proceed imperceptibly slowly if the activation energy is high. c) If K≈1K\approx 1, the reaction will proceed rapidly in both directions because the energy barrier is low. d) Because a negative ΔG∘\Delta G^{\circ} means the reaction is spontaneous, it cannot be kinetically hindered.

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