Chemistry

Chemistry

Problem

At 298 K the uncatalyzed hydrolysis of compound Y has a rate constant ku=2.0×10−6 s−1k_{u}=2.0\times10^{-6}\,\text{s}^{-1} and an activation energy of 88 kJ mol−1^{-1}. A solid catalyst lowers the activation energy to 60 kJ mol−1^{-1} but does not change the pre-exponential factor. What is the expected catalyzed rate constant at 298 K? (Use R=8.314 J mol−1K−1R = 8.314\,\text{J mol}^{-1}\text{K}^{-1}.) a) 8.0×10−4 s−18.0 \times 10^{-4}\,\text{s}^{-1} b) 2.3×10−5 s−12.3 \times 10^{-5}\,\text{s}^{-1} c) 1.6×10−1 s−11.6 \times 10^{-1}\,\text{s}^{-1} d) 2.0×10−6 s−12.0 \times 10^{-6}\,\text{s}^{-1}

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