Chemistry

Chemistry

Problem

Two gas-phase elementary reactions occur separately at 298 K. I. Cl + CH₃Br → CH₃Cl + Br (Ea = 12 kJ mol⁻¹) II. NO + O₃ → NO₂ + O₂ (Ea = 95 kJ mol⁻¹) Assuming comparable collision frequencies and orientations, which statement best compares their instantaneous reaction rates at 298 K? a) Reaction II is faster because a higher activation energy leads to more energetic collisions. b) Both reactions proceed at nearly the same rate since they are carried out at the same temperature. c) Reaction I is faster primarily because a larger fraction of collisions exceed the required energy. d) Reaction II is faster because forming stronger bonds in the products releases more energy, accelerating the reaction.

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