Chemistry

Chemistry

Problem

In a 1.0-L flask at 500\,K the reaction CO(g)+H2O(g)⇌CO2(g)+H2(g)\mathrm{CO(g)}+\mathrm{H_2O(g)} \rightleftharpoons \mathrm{CO_2(g)}+\mathrm{H_2(g)} is at equilibrium with all four species present at 1.0 M. Three separate disturbances are made to identical flasks, producing conditions I–III. • Disturbance I: [CO] is doubled to 2.0 M and [CO2_2] is halved to 0.50 M (others unchanged). • Disturbance II: The volume is doubled to 2.0 L at constant TT (no moles added or removed). • Disturbance III: [H2_2O] is reduced to 0.50 M and [H2_2] is increased to 1.5 M (others unchanged). Which ranking orders the disturbances from the strongest driving force toward products (rightward shift) to the strongest driving force toward reactants (leftward shift)? a) II > I > III b) I > III > II c) I > II > III d) III > II > I

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