Callen H.B - Thermodynamics And An Introduction To Thermostatistics · Problem 2.3-4

SOME FORMAL RELATIONSHIPS, AND SAMPLE SYSTEMS

Physics — Statistical Mechanics · permissible-fundamental-equation-constants

Problem

Consider the fundamental equation S=AUnVmNrS = AU^n V^m N^r where AA is a positive constant. Evaluate the permissible values of the three constants nn, mm, and rr if the fundamental equation is to satisfy the thermodynamic postulates and if, in addition, we wish to have PP increase with U/VU/V, at constant NN. (This latter condition is an intuitive substitute for stability requirements to be studied in Chapter 8.) For definiteness, the zero of energy is to be taken as the energy of the zero-temperature state.

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