Statistical Mechanics · Problem 5.2

The Theory of Simple Gases — R. K. Pathria

Physics — Statistical Mechanics · density-matrix-coordinate-representation

Problem

Prove that ⟨q∣e−βH^∣q′⟩≡exp⁡[−βH^(−iℏ∂∂q,q)]δ(q−q′),\langle q|e^{-\beta\hat{H}}|q'\rangle \equiv \exp\left[-\beta\hat{H}\left(-i\hbar\frac{\partial}{\partial q}, q\right)\right]\delta(q-q'), where H^(−iℏ ∂/∂q,q)\hat{H}(-i\hbar\,\partial/\partial q, q) is the Hamiltonian of the system, in the qq-representation, which formally operates upon the Dirac delta function δ(q−q′)\delta(q-q'). Writing the δ\delta-function in a suitable form, apply this result to (i) a free particle and (ii) a linear harmonic oscillator.

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