Copper sulphate is prepared by blowing a current of air through copper scrap and dilute H2SO4 . Dilute HNO3 is also added :
a. to oxidise copper to Cu2+ which then form CuSO4 with dilute H2SO4
b. to oxidise Fe2+ to iron (III) sulphate, which remains in solution after crystallisation of CuSO4
c. to speed up the ionisation of H2SO4 to give SO42− ions
d. which combines with H2SO4 to give a very strong oxidising mixture and oxidises Cu to Cu2+