Chemistry

Chemistry

Problem

Consider the formation of HI from H2\mathrm{H_2} and I2\mathrm{I_2} in the gas phase. Two individual collisions are described below. Collision X: An H2\mathrm{H_2} molecule approaches an I2\mathrm{I_2} molecule end-to-end so that one H atom is pointed directly at one I atom. Collision Y: The same H2\mathrm{H_2} molecule approaches the midpoint of the I2\mathrm{I_2} molecule at a right angle (side-on). Which statement about the likelihood of these collisions leading to product formation best reflects kinetic theory? a) Only Collision Y is likely to produce HI\mathrm{HI} because it maximizes the surface contact between H2\mathrm{H_2} and I2\mathrm{I_2}, allowing bonds to break simultaneously. b) Both collisions are unlikely to produce HI\mathrm{HI} because breaking two bonds and forming two new ones is statistically improbable in a single collision. c) Only Collision X is likely to produce HI\mathrm{HI} because it aligns the atoms that must exchange bonds. d) Both collisions will produce HI\mathrm{HI} with equal probability as long as the temperature is high enough, since collision energy is the dominant factor.

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