Temperature-Dependent Specific Heat · Physics Brawl 2019 #FoL.16

Physics · thermodynamics

Problem

Jindra was interested in the magnitude of error in the problem "one hundred". The specific heat of water is in fact temperature-dependent. Jindra found an empirical relationship for the specific heat cwater=3.1832⋅10−6t4−7.7922⋅10−4t3+7.5387⋅10−2t2−2.9190t+4.2158⋅103c_{water} = 3.1832 \cdot 10^{-6}t^4 - 7.7922 \cdot 10^{-4}t^3 + 7.5387 \cdot 10^{-2}t^2 - 2.9190t + 4.2158 \cdot 10^3 where the temperature tt must be in °C and the specific heat is obtained in J·kg⁻¹·K⁻¹. What is the difference (in percent) between the heat supplied to water with a constant specific heat c=4184.0c = 4184.0 J·kg⁻¹·K⁻¹ and the heat calculated using the empirical relationship, if the mass of this water is m=1.00m = 1.00 kg and its temperature increases from 0.00°C to 100.00°C in both cases? The sign of the result is important (i.e. if the amount of heat for the case with constant specific heat is lower, we expect a negative sign).

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