Calcium fluoride has a solubility-product constant of 2.0×10−11 at 35∘C and 5.0×10−12 at 15∘C. A chemist prepares 1.00L of a solution saturated with CaF2 at 35∘C and then cools the solution to 15∘C, keeping the volume constant. What mass of CaF2 (molar mass 78.07g/mol) will precipitate upon cooling?
a) 0.0078g
b) 0.0050g
c) 0.00050g
d) 0.0084g