An 18.0g sample of a metal with molar mass 27.0gmol−1 is heated to 105.0∘C and transferred to 75.0g of water at 20.0∘C in a calorimeter whose heat capacity is 40.0J∘C−1. The system reaches a final temperature of 23.2∘C. Using 4.18Jg−1∘C−1 for water, what is the molar heat capacity of the metal?
a) 18.4Jmol−1∘C−1
b) 28.2Jmol−1∘C−1
c) 20.7Jmol−1∘C−1
d) 9.2Jmol−1∘C−1