A localized distribution of charge has a charge density
ρ(r)=64π1r2e−rsin2θ
((a)) Make a multipole expansion of the potential due to this charge density and determine all the nonvanishing multipole moments. Write down the potential at large distances as a finite expansion in Legendre polynomials.
((b)) Determine the potential explicitly at any point in space, and show that near the origin, correct to r2 inclusive,
Φ(r)≈4πϵ01[41−120r2P2(cosθ)]
((c)) If there exists at the origin a nucleus with a quadrupole moment Q=10−28 m2, determine the magnitude of the interaction energy, assuming that the unit of charge in ρ(r) above is the electronic charge and the unit of length is the hydrogen Bohr radius a0=4πϵ0ℏ2/me2=0.529×10−10 m. Express your answer as a frequency by dividing by Planck's constant h.
The charge density in this problem is that for the m=±1 states of the 2p level in hydrogen, while the quadrupole interaction is of the same order as found in molecules.