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Chemistry
Chemistry
Problem
What ratio of
Pb
2
+
\text{Pb}^{2+}
Pb
2
+
to
Sn
2
+
\text{Sn}^{2+}
Sn
2
+
concentration is needed to reverse the following cell reaction?
Sn
(
s
)
+
Pb
(
a
q
.
)
2
+
⇌
Sn
(
a
q
.
)
2
+
+
Pb
(
s
)
\text{Sn}(s) + \text{Pb}(aq.)^{2+} \rightleftharpoons \text{Sn}(aq.)^{2+} + \text{Pb}(s)
Sn
(
s
)
+
Pb
(
a
q
.
)
2
+
⇌
Sn
(
a
q
.
)
2
+
+
Pb
(
s
)
E
Sn
2
+
/
Sn
∘
=
−
0.136
V
and
E
Pb
2
+
/
Pb
∘
=
−
0.126
V
E_{\text{Sn}^{2+}/\text{Sn}}^\circ = -0.136\text{V} \quad \text{and} \quad E_{\text{Pb}^{2+}/\text{Pb}}^\circ = -0.126\text{V}
E
Sn
2
+
/
Sn
∘
=
−
0.136
V
and
E
Pb
2
+
/
Pb
∘
=
−
0.126
V
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