The [H+] in 0.2 M solution of formic acid is 6.4×10−3 mol litre-1. To this solution formate is added so as to adjust the conc. of sodium formate to one mol per litre. What will be pH of this solution? Ka for HCOOH is 2.4×10−4 and degree of dissociation of HCOONa is 0.75.