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Chemistry
Chemistry
Problem
For the electrochemical cell,
M
∣
M
+
∣
∣
X
−
∣
X
M | M^+ || X^- | X
M
∣
M
+
∣∣
X
−
∣
X
E
(
M
+
/
M
)
∘
=
0.44
V
E_{(M^+/M)}^{\circ} = 0.44 \text{ V}
E
(
M
+
/
M
)
∘
=
0.44
V
and
E
(
X
/
X
−
)
∘
=
0.33
V
E_{(X/X^-)}^{\circ} = 0.33 \text{ V}
E
(
X
/
X
−
)
∘
=
0.33
V
. From this data one can deduce that : (IIT 2000) a.
M
+
X
⟶
M
+
+
X
−
M + X \longrightarrow M^+ + X^-
M
+
X
⟶
M
+
+
X
−
is the spontaneous reaction b.
M
+
+
X
−
⟶
M
+
X
M^+ + X^- \longrightarrow M + X
M
+
+
X
−
⟶
M
+
X
is the spontaneous reaction c.
E
cell
=
0.77
V
E_{\text{cell}} = 0.77 \text{ V}
E
cell
=
0.77
V
d.
E
cell
=
−
0.77
V
E_{\text{cell}} = -0.77 \text{ V}
E
cell
=
−
0.77
V
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