Chemistry

Chemistry

Problem

For the electrochemical cell, M∣M+∣∣X−∣XM | M^+ || X^- | X E(M+/M)∘=0.44 VE_{(M^+/M)}^{\circ} = 0.44 \text{ V} and E(X/X−)∘=0.33 VE_{(X/X^-)}^{\circ} = 0.33 \text{ V} . From this data one can deduce that : (IIT 2000) a. M+X⟶M++X−M + X \longrightarrow M^+ + X^- is the spontaneous reaction b. M++X−⟶M+XM^+ + X^- \longrightarrow M + X is the spontaneous reaction c. Ecell=0.77 VE_{\text{cell}} = 0.77 \text{ V} d. Ecell=−0.77 VE_{\text{cell}} = -0.77 \text{ V}

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