Griffiths Introduction to Elementary Particles · Problem 5.12
The Feynman Calculus — David J. Griffiths
Physics — QFT · expectation-value-tensor-operator
Problem
Suppose A and B are two fixed vectors. Show that the expectation value of
Q≡[3(A⋅r^)(B⋅r^)−(A⋅B)]
is zero in any spherically symmetrical state. [Hint: First convince yourself that ⟨Q⟩ must be proportional to (A⋅B):
⟨Q⟩=α(A⋅B)
where α, the proportionality constant, is independent of A and B. To evaluate α, take the case where A and B are parallel, and choose the z axis to lie along this direction. Then
α=⟨(3cos2θ−1)⟩
Now perform the θ integral. [Notice that the argument is not affected if an arbitrary function of r is thrown into the expectation value. In particular, the expectation value of the first term in equation (5.59) must vanish for an electron in the S state.]]