When a reagent (X) reacts with Fe3+ salt solution turns red due to the formation of a compound (Y). This reagent causes no change in colour with Fe2+ salt solution. Compound (X) and (Y) are respectively :
a. NH4SCN and Fe(SCN)3
b. K4[Fe(CN)6] and FeSO4
c. Na2HPO4 and FeSO4
d. K3[Fe(CN)6] and K2Fe[Fe(CN)6]