Vapour pressure of CH3Cl and CH2Cl2 are 540 mm Hg and 402 mm Hg respectively. 101 g of CH3Cl and 85 g of CH2Cl2 are mixed together. Determine:
a. The pressure at which the solution starts boiling.
b. Molar ratio of solute v/s solvent in vapour phase in equilibrium with solution.