Chemistry

Chemistry

Problem

- A yellow precipitate of the compound A is formed on passing H2S\text{H}_2\text{S} through a neutral solution of the salt B. - The compound A is soluble in hot dilute HNO3\text{HNO}_3 but insoluble in yellow ammonium sulphide. - The solution of B, on treatment with a small quantity of NH3\text{NH}_3 , gives a white precipitate soluble in an excess of the reagent, forming a compound C. - The solution of B gives a white precipitate with a small concentration of KCN. The precipitate is soluble in an excess of the reagent, forming a compound D. - The solution of D, on treatment with H2S\text{H}_2\text{S} , gives A. - The solution of B in dilute HCl\text{HCl} , on treatment with a solution of BaCl2\text{BaCl}_2 , gives a white precipitate of the compound E, which is almost insoluble in concentrated HNO3\text{HNO}_3 . - Which of the following anions is present in B ? a. SO42−\text{SO}_4^{2-} b. CO32−\text{CO}_3^{2-} c. SO32−\text{SO}_3^{2-} d. S2−\text{S}^{2-}

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