Statistical Mechanics · Problem 3.2

The Grand Canonical Ensemble — R. K. Pathria

Physics — Statistical Mechanics · canonical-ensemble-energy-fluctuations

Problem

Prove that the quantity g′′(x0)g''(x_0), see eqn. (3.2.25), is equal to ⟨(E−U)2⟩exp⁡(2β)\langle (E - U)^2 \rangle \exp(2\beta). Hence show that eqn. (3.2.28) is physically equivalent to eqn. (3.6.9).

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