Chemistry

Chemistry

Problem

Acid HXOn\mathrm{HXO_n} contains a single O–H bond and a central atom X. The analogous acid HYOn\mathrm{HYO_n} contains the same number of oxygen atoms, but the central atom Y is in the same period as X. If X has an electronegativity of 2.5 and Y has an electronegativity of 3.0, which statement about their pKapK_a values is most accurate? a) Both acids have identical pKapK_a values because they contain the same number of oxygen atoms. b) HYOn\mathrm{HYO_n} has a larger pKapK_a because its conjugate base is more stabilized. c) HYOn\mathrm{HYO_n} is a weaker acid because its higher electronegativity strengthens the O–H bond. d) HYOn\mathrm{HYO_n} has a smaller pKapK_a because its conjugate base is more stabilized.

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