Chemistry

Chemistry

Problem

Consider the given data: 1. Cr2O72−+14H++6e−⇌2Cr3++7H2O1.33\text{Cr}_2\text{O}_7^{2-} + 14\text{H}^+ + 6\text{e}^- \rightleftharpoons 2\text{Cr}^{3+} + 7\text{H}_2\text{O} \quad 1.33 2. Cr3++3e−⇌Cr−0.74\text{Cr}^{3+} + 3\text{e}^- \rightleftharpoons \text{Cr} \quad -0.74 3. Cu++e−⇌Cu0.52\text{Cu}^+ + \text{e}^- \rightleftharpoons \text{Cu} \quad 0.52 4. Cu2++2e−⇌Cu0.34\text{Cu}^{2+} + 2\text{e}^- \rightleftharpoons \text{Cu} \quad 0.34 The numerical value of the standard cell potential for the reaction 2Cr(s)+3Cu2+(aq)⇌2Cr3+(aq)+3Cu(s)2\text{Cr}(\text{s}) + 3\text{Cu}^{2+}(\text{aq}) \rightleftharpoons 2\text{Cr}^{3+}(\text{aq}) + 3\text{Cu}(\text{s}) is (a) −1.08 Volts-1.08\,\text{Volts} (b) −0.40 Volts-0.40\,\text{Volts} (c) 1.08 Volts1.08\,\text{Volts} (d) 2.50 Volts2.50\,\text{Volts}

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