Callen H.B - Thermodynamics And An Introduction To Thermostatistics · Problem 7.4-1

STABILITY OF THERMODYNAMIC SYSTEMS

Physics — Statistical Mechanics · joule-thomson-derivative-reduction

Problem

In the analysis of a Joule--Thomson experiment we may be given the initial and final molar volumes of the gas, rather than the initial and final pressures. Express the derivative (∂T/∂v)h\left(\partial T/\partial v\right)_h in terms of cpc_p, α\alpha, and κT\kappa_T.

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