A laboratory technician prepares four aqueous mixtures at 25 °C, each by combining the stated volumes of 0.10 M acetic acid, HC₂H₃O₂, and 0.10 M NaOH. In which mixture will the resulting solution best resist changes in pH when a small amount of strong acid or base is added?
I. 25 mL HC₂H₃O₂ + 25 mL NaOH
II. 50 mL HC₂H₃O₂ + 25 mL NaOH
III. 25 mL HC₂H₃O₂ + 50 mL NaOH
IV. 75 mL HC₂H₃O₂ + 75 mL NaOH
a) I only
b) IV only
c) II only
d) I and II