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Chemistry
Chemistry
Problem
For the cell
Mg(s)
∣
Mg
2
+
(
aq.
)
∣
∣
Ag
+
(
aq.
)
∣
Ag(s)
\text{Mg(s)} | \text{Mg}^{2+}(\text{aq.}) || \text{Ag}^+(\text{aq.}) | \text{Ag(s)}
Mg(s)
∣
Mg
2
+
(
aq.
)
∣∣
Ag
+
(
aq.
)
∣
Ag(s)
, calculate the equilibrium constant at
25
∘
C
25^\circ\text{C}
2
5
∘
C
and the maximum work that can be obtained during operation of cell. Given,
E
Mg
/
Mg
2
+
∘
=
+
2.37
V
and
E
Ag
+
/
Ag
∘
=
+
0.80
V
,
E^\circ_{\text{Mg}/\text{Mg}^{2+}} = +2.37\text{V} \quad \text{and} \quad E^\circ_{\text{Ag}^+/\text{Ag}} = +0.80\text{V},
E
Mg
/
Mg
2
+
∘
=
+
2.37
V
and
E
Ag
+
/
Ag
∘
=
+
0.80
V
,
R
=
8.314
J
R = 8.314\text{ J}
R
=
8.314
J
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