An unknown element produces two peaks in its mass spectrum at m/z=64 and m/z=66. The peak at 64 has twice the relative intensity of the peak at 66. Which of the following best describes the natural isotopic composition of the element?
a) approximately 50\% 64X and 50\% 66X
b) approximately 67\% 64X and 33\% 66X
c) approximately 75\% 64X and 25\% 66X
d) approximately 33\% 64X and 67\% 66X