Blundell Thermal Physics · Problem 28.3

Phase transitions

Physics — Statistical Mechanics · clausius-clapeyron-ice-water

Problem

The gradient of the melting line of water on a pp–TT diagram close to 0∘0^\circC is −1.4×107-1.4 \times 10^7 Pa K−1^{-1}. At 0∘0^\circC, the specific volume of water is 1.00×10−31.00 \times 10^{-3} m3^3 kg−1^{-1} and of ice is 1.09×10−31.09 \times 10^{-3} m3^3 kg−1^{-1}. Using this information, deduce the latent heat of fusion of ice. In winter, a lake of water is covered initially by a uniform layer of ice of thickness 1 cm. The air temperature at the surface of the ice is −0.5∘-0.5^\circC. Estimate the rate at which the layer of ice begins to thicken, assuming that the temperature of the water just below the ice is 0∘0^\circC. You can also assume steady-state conditions and ignore convection. The temperature of the water at the bottom of the lake, depth 1 m, is maintained at 2∘2^\circC. Find the thickness of ice that will eventually be formed. [[The thermal conductivity of ice is 2.32.3 W m−1^{-1} K−1^{-1} and of water is 0.560.56 W m−1^{-1} K−1^{-1}.]]

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