Chemistry

Chemistry

Problem

The thermal decomposition of calcium carbonate is described by CaCO3(s)→CaO(s)+CO2(g)ΔH∘=+178 kJ\text{CaCO}_3(s)\rightarrow \text{CaO}(s)+\text{CO}_2(g)\qquad \Delta H^{\circ}=+178\,\text{kJ} Given: ΔHf∘(CaCO3(s))=−1207 kJ mol−1\Delta H_f^{\circ}(\text{CaCO}_3\text{(s)}) = -1207\,\text{kJ mol}^{-1} ΔHf∘(CO2(g))=−393.5 kJ mol−1\Delta H_f^{\circ}(\text{CO}_2\text{(g)}) = -393.5\,\text{kJ mol}^{-1} Determine ΔHf∘(CaO(s))\Delta H_f^{\circ}(\text{CaO}\text{(s)}). a) +5.72×102 kJ mol−1+5.72\times10^{2}\,\text{kJ mol}^{-1} b) −2.15×102 kJ mol−1-2.15\times10^{2}\,\text{kJ mol}^{-1} c) −6.36×102 kJ mol−1-6.36\times10^{2}\,\text{kJ mol}^{-1} d) −9.92×102 kJ mol−1-9.92\times10^{2}\,\text{kJ mol}^{-1}

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