Statistical Mechanics · Problem 6.22

Ideal Bose Systems — R. K. Pathria

Physics — Statistical Mechanics · morse-potential-hydrogen-rotational-vibrational

Problem

The potential energy between the atoms of a hydrogen molecule is given by the (semi-empirical) Morse potential V(r)=V0{e−2(r−r0)/a−2e−(r−r0)/a},V(r) = V_0\left\{e^{-2(r-r_0)/a} - 2e^{-(r-r_0)/a}\right\}, where V0=7×10−12V_0 = 7 \times 10^{-12} erg, r0=8×10−9r_0 = 8 \times 10^{-9} cm and a=5×10−9a = 5 \times 10^{-9} cm. Calculate the rotational and vibrational quanta of energy, and estimate the temperatures at which the rotational and vibrational modes of the molecules would begin to contribute towards the specific heat of the hydrogen gas.

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