Chemistry

Chemistry

Problem

In the equilibrium expression for the reaction H2O(l)+CO32−(aq)⇌HCO3−(aq)+OH−(aq),\text{H}_2\text{O}(l)+\text{CO}_3^{2-}(aq)\rightleftharpoons\text{HCO}_3^{-}(aq)+\text{OH}^-(aq), water does not appear explicitly. Which of the following best explains this omission? a) Including water would change the units of KK, so chemists leave it out to keep KK unitless. b) Water is the solvent, so all solvent species are automatically left out of equilibrium expressions. c) The concentration of pure liquid water is effectively constant and is built into the equilibrium constant. d) By convention, the molar concentration of water is fixed at 1 M1\,\text{M}, so it cancels from the expression.

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